不同海域沉积物对尿素吸附的实验模拟研究     

薛峤娜  胡博  谭丽菊  王江涛 《海洋学报》2018,40(10):190-199

本文对采自渤海、黄海和东海3个典型海域的沉积物进行了尿素吸附/解吸的实验室模拟研究，用Freundlich吸附模型和Henry吸附模型分析了不同沉积物对尿素吸附的热力学特性，并研究了温度、沉积物粒径、有机质含量等因素对尿素在沉积物表面吸附的影响。结果表明，沉积物对尿素的吸附/解吸过程总体呈现3个阶段:快速吸附阶段（0~5 h）—慢速吸附阶段（5~12 h）—平衡阶段（12 h之后）。当水体中的尿素浓度较低时，沉积物解吸释放尿素，随着上覆水中尿素浓度逐渐增加，沉积物对上覆水中的尿素产生吸附行为，各海区沉积物对尿素的吸附能力由强至弱依次为渤海、东海、黄海，这可能与沉积物的类型有关。Freundlich方程和Henry方程均可模拟沉积物对尿素的吸附，温度、粒径以及沉积物中有机质含量等因素均对尿素在沉积物上的吸附产生影响，随着温度升高，尿素在沉积物上的吸附量变小，沉积物粒径越小，有机质含量越高，吸附尿素的能力越强，因此，揭示尿素在沉积物表面的环境行为时，必须考虑以上因素的影响。  相似文献   

Dispersion features of transmitted channel waves and inversion of coal seam thickness     

Ze’an Hu  Pingsong Zhang  Guangquan Xu 《Acta Geophysica》2018,66(5):1001-1009

In-seam seismic survey currently is a hot geophysical exploration technology used for the prediction of coal seam thickness in China. Many studies have investigated the relationship between the group velocity of channel wave at certain frequency and the actual thickness of exposed coal beds. But these results are based on statistics and not universally applicable to predict the thickness of coal seams. In this study, we first theoretically analyzed the relationship between the depth and energy distribution of multi-order Love-type channel waves and found that when the channel wave wavelength is smaller than the thickness of the coal seam, the energy is more concentrated, while when the wavelength is greater than the thickness, the energy reduces linearly. We then utilized the numerical simulation technology to obtain the signal of the simulated Love-type channel wave, analyzed its frequency dispersion, and calculated the theoretical dispersion curves. The results showed that the dispersion characteristics of the channel wave are closely related to the thickness of coal seam, and the shear wave velocity of the coal seam and its surrounding rocks. In addition, we for the first time realized the joint inversion of multi-order Love-type channel waves based on the genetic algorithm and inversely calculated the velocities of shear wave in both coal seam and its surrounding rocks and the thickness of the coal seam. In addition, we found the group velocity dispersion curve of the single-channel transmitted channel wave using the time–frequency analysis and obtained the phase velocity dispersion curve based on the mathematical relationship between the group and phase velocities. Moreover, we employed the phase velocity dispersion curve to complete the inversion of the above method and obtain the predicted coal seam thickness. By comparing the geological sketch of the coal mining face, we found that the predicted coal seam thickness is in good agreement with the actual thickness. Overall, adopting the channel wave inversion method that creatively uses the complete dispersion curve can obtain the shear wave velocities of the coal and its surrounding rocks, and analyzing the depth of the abruptly changed shear wave velocity can accurately obtain the thickness of the coal seam. Therefore, our study proved that this inversion method is feasible to be used in both simulation experiments and actual detection.  相似文献   

The role of fog,orography, and seasonality on precipitation in a semiarid,tropical island          下载免费PDF全文

Sarah R. Schmitt  Diego A. Riveros‐Iregui  Jia Hu 《水文研究》2018,32(18):2792-2805

Isotopes of water (²H/¹H and ¹⁸O/¹⁶O) are commonly used to trace hydrological processes such as moisture recycling, evaporation loss, and moisture source region and often vary temporally in a given region. This study provides a first‐ever characterization of temporally variable precipitation mechanisms of San Cristóbal Island, Galápagos. We collected fog, rain, and throughfall samples over three field seasons to understand the mechanisms driving seasonal‐ and event‐based variability in the isotopic composition of precipitation in Galápagos. We establish that fog is a common phenomenon in San Cristóbal, especially during the dry season, and we found that fog, compared with cocollected rainfall, is consistently enriched. We further suggest that the relative contribution of fog formed via different mechanisms (orographic, advective, radiation) varied seasonally. We found that the source region is the most dominant control of the isotopic composition of rainfall in the Galápagos at both the seasonal and event scales, but subcloud evaporative processes (the nontraditional manifestation of the amount effect) became a dominant control on the isotopic composition of rainfall during the dry season. Overall, our findings suggest that understanding seasonally variable water‐generating mechanisms is required for effective water resource management in San Cristóbal Island and other semiarid island ecosystems under current and future regimes of climate change.  相似文献   

Precise Location of Earthquakes at the Eastern Boundaries of the Sichuan-Yunnan Rhombic Block     

Fu Ying  Hu Bin  Long Feng  Wang Shiyuan 《中国地震研究》2018,32(4):470-481

Based on the seismic station data sets from Sichuan and Yunnan provinces, we employed a multi-step seismic location method (Hypo2000 + Velest + HypoDD) to precisely locate the 7,787 earthquakes that occurred during 2010-2015 along the eastern boundaries of the Sichuan-Yunnan rhombic block, namely from southern Dawu to the Qiaojia segment. The final results show that location precision is greatly advanced and epicenter distribution exhibits good consistency with the linear distribution of the seismic faults. Earthquake distribution is quite intensive at the intersection region in the southern segment of the Xianshuihe fault, the Anninghe fault zone, the Xiaojinhe fault zone and the Daliangshan fault zone to the east. The depth profile of seismicity shows a clear stepwise activity along the active seismic fault zones. The profile crossing the faults of the Xianshuihe, Anninghe, and Daliangshan presents a complex interaction among faults near the multiple faults intersection region, Shimian, where the earthquakes are obviously divided into two groups in depth. Earthquakes are very rare at the depth of 15km-20km, which is consistent with the region of the plastic rheology between 14km-19km calculated by Zhu Ailan et al.,(2005).  相似文献   

基于开放大数据的广州市中心城区职住平衡特征研究     

林勋媛  王广兴  胡月明 《热带地理》2020,40(2):254-265

以广州市中心城区为例,借助百度热力图、百度实时路况和百度地图POI数据,从中观层面多角度综合分析广州市中心城区就业与居住的空间分布关系。结果显示：1）工作时间段人口聚集的高值区整体呈带状分布,斑块较为细碎,但绝大部分集中在核心地带;人口主要高度集中于各区的商业繁华地段与交通线路周围。而休息时间段的高值区则相对集中分布,用地效率较高,表现出多中心的圈层结构;人口主要高度集中分布在传统的老城居住区和新开发的商业住宅区,与核心商圈相对错开。2）不管是在上班时段还是休息时段,人口聚集程度越高的地区,POI设施密度表现越显著;这意味着人口的聚集具有一定的选择性,主要集中在城市基础设施发展较完备的区域。3）广州市中心城区各街道的职住比介于0.73~1.54,职住相对平衡,区域之间差异较小。其中,分值较高的街道多分布于核心地带（主要集中在越秀区、荔湾区北部和天河区南部）,分值较低的街道多分布于核心地带的外围或边缘地区（主要在海珠区、荔湾区和白云区零散分布）。4）从城市交通响应上看,广州市中心城区工作日内早高峰的拥堵度大于晚高峰,但总体路况变化跨度不大,区内并没有出现特别严重的“潮汐通勤”现象。  相似文献   

南沙他国侵占岛礁战略价值及空间格局评价     

闵开付  程亮  周晓  夏南  李宁  李满春 《热带地理》2020,40(4):684-693

从建岛潜力、岛礁辐射能力和岛礁承载能力3个方面选取26个指标，采用主客观综合赋权法确定各因子权重，利用线性加权法获得被越南、菲律宾、马来西亚、文莱等国所侵占的南沙44个岛礁的战略价值，并对结果进行空间插值，分析其空间格局特征。结果表明：1）被马来西亚侵占的弹丸礁、越南侵占的南威岛、以及菲律宾侵占的中业岛，其战略价值位列前3，评价得分分别为100、98.42和97.09。2）岛礁辐射能力空间分布格局呈现“NW—SE条带式”，“最高”和“高”等级的区域由研究区西北延伸至东南，然后向东北、西南两侧递减，辐射能力格局中有2个核心区域和2个次级核心区域。承载能力空间分布格局呈现“横向条带式”，由北向南越来越低，有1个核心区域和2个次级核心区域。建岛潜力空间分布格局有3个核心区域及2个次级核心区域。3）岛礁战略价值空间分布格局有3个核心区域，分布于研究区中部、北部及南部，与越南、菲律宾、马来西亚密切相关的核心区域各有1个。越南侵占岛礁最多且空间分布较广，有2个次级核心区域也与越南密切相关，越占岛礁若进一步建设，将形成多核心协同的战略格局，需密切关注。  相似文献   

地缘政治风险研究进展与展望     

熊琛然  王礼茂  屈秋实  向宁  王博 《地理科学进展》2020,39(4):695-706

地缘政治风险是影响全球和区域和平、稳定与发展的5大风险之一。如何识别、评估、预测和管理地缘政治风险成为国内外共同关注的问题。国内外学者对地缘政治风险这一术语的定义还不统一。当前地缘政治风险研究,在致险因素分析、风险影响刻画、风险量化与制图等领域都有一些新进展。针对地缘政治风险致险因子的时空差异性和多变性、各致险因子相互影响与反馈机制的复杂性以及地缘政治风险的突发性和不确定性,对致险因素的精准识别,地缘政治风险形成的机理,地缘政治风险监测与模拟等研究成为核心和前沿问题。中国未来地缘政治风险和重要研究方向包括：周边地区地缘政治风险研究;地缘政治风险的定量化与模拟研究;跨学科、大数据、多终端的地缘政治风险集成计算方法与预警服务平台建设;凝炼科学问题,提升对现实地缘政治问题的解释能力。  相似文献   

Feasibility of Re-injecting the Production Effluent from Alkali–Surfactant–Polymer Flooding Systems Back into a Reservoir to Further Improve Oil Recovery     

Zhang  Chengli  Hu  Bozhou  Wang  Peng  Fu  Xiaofei  Song  Guoliang  Liu  Haoliang 《Natural Resources Research》2020,29(3):2191-2207

Natural Resources Research - Alkali–surfactant–polymer (ASP)-produced effluent contains polymer, alkali and surfactant, and it has higher content of suspended oil droplets and suspended...  相似文献   

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Coordinative similitude law considering fluid‐structure interaction for underwater shaking table tests     

Zhong‐Xian Li  Kun Wu  Yundong Shi  Ning Li  Yang Ding 《地震工程与结构动力学》2018,47(11):2315-2332

Generally, when a model is made of the same material as the prototype in shaking table tests, the equivalent material density of the scaled model is greater than that of the prototype because mass is added to the model to satisfy similitude criteria. When the water environment is modeled in underwater shaking table tests, however, it is difficult to change the density of water. The differences in the density similitude ratios of specimen materials and water can affect the similitude ratios of the hydrodynamic and wave forces with those of other forces. To solve this problem, a coordinative similitude law is proposed for underwater shaking table tests by adjusting the width of the upstream face of the model or the wave height in the model test to match the similitude ratios of hydrodynamic and wave forces with those of other forces. The designs of the similitude relations were investigated for earthquake excitation, wave excitation, and combined earthquake and wave excitation conditions. Series of numerical simulations and underwater shaking table tests were performed to validate the proposed coordinative similitude law through a comparison of coordinative model and conventional model designed based on the coordinative similitude law and traditional artificial mass simulation, respectively. The results show that the relative error was less than 10% for the coordinative model, whereas it reached 80% for the conventional model. The coordinative similitude law can better reproduce the dynamic responses of the prototype, and thus, this similitude law can be used in underwater shaking table tests.  相似文献